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So I got a Maul and Staff + bonecrusher, herbicide, herblore/smithing scrolls. What should I get for the third chaotic?

I'm going to be bossing, if that helps.

Get the imp that collects charms.
That's VERY VERY useful. I find collecting charms tedious and cannot wait to be able to own the imp.

Can't really comment on what chaotic weapon as I don't own any of them.

Get the charming imp, Its really useful. OR get the chaotic crossbow.

After imp I'd say a shield if you are low level as dung shields are the best in the game but than again using defensive shields is bad period.

Unless you are tanking nex provoking KK.